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Abstract We present observations of population anti-inversion in the 3₁− 4₀A⁺transition of CH₃OH (methanol) at 107.013831 GHz toward the Galactic center cloud G0.253+0.016 (“The Brick”). Anti-inversion of molecular level populations can result in absorption lines against the cosmic microwave background (CMB) in a phenomenon known as a “dasar.” We model the physical conditions under which the 107 GHz methanol transition dases and determine that dasing occurs at densities below 10⁶cm⁻³and column densities between 10¹³and 10¹⁶cm⁻². We also find that for this transition, dasing does not strongly depend on the gas kinetic temperature. We evaluate the potential of this tool for future deep galaxy surveys. We note that other works have already reported absorption in this transition (e.g., in NGC 253), but we provide the first definitive evidence that it is absorption against the CMB rather than against undetected continuum sources. 

Abstract We report the discovery of nine new hot molecular cores in the Deep South (DS) region of Sagittarius B2 using Atacama Large Millimeter/submillimeter Array Band 6 observations. We measure the rotational temperature of CH₃OH and derive the physical conditions present within these cores and the hot core Sgr B2(S). The cores show heterogeneous temperature structure, with peak temperatures between 252 and 662 K. We find that the cores span a range of masses (203–4842M_⊙) and radii (3587–9436 au). CH₃OH abundances consistently increase with temperature across the sample. Our measurements show the DS hot cores are structurally similar to Galactic disk hot cores, with radii and temperature gradients that are comparable to sources in the disk. They also show shallower density gradients than disk hot cores, which may arise from the Central Molecular Zone’s higher density threshold for star formation. The hot cores have properties which are consistent with those of Sgr B2(N), with three associated with Class II CH₃OH masers and one associated with an ultra-compact Hiiregion. Our sample nearly doubles the high-mass star-forming gas mass near Sgr B2(S) and suggests the region may be a younger, comparably massive counterpart to Sgr B2(N) and (M). The relationship between peak CH₃OH abundance and rotational temperature traced by our sample and a selection of comparable hot cores is qualitatively consistent with predictions from chemical modeling. However, we observe constant peak abundances at higher temperatures (T≳ 250 K), which may indicate mechanisms for methanol survival that are not yet accounted for in models. 

Abstract We report JWST NIRCam observations of G0.253+0.016, the molecular cloud in the Central Molecular Zone known as “The Brick,” with the F182M, F187N, F212N, F410M, F405N, and F466N filters. We catalog 56,146 stars detected in all six filters using thecrowdsourcepackage. Stars within and behind The Brick exhibit prodigious absorption in the F466N filter that is produced by a combination of CO ice and gas. In support of this conclusion, and as a general resource, we present models of CO gas and ice and CO₂ice in the F466N, F470N, and F410M filters. Both CO gas and ice contribute to the observed stellar colors. We show, however, that CO gas does not absorb the Pfβand Huϵlines in F466N, but that these lines show excess absorption, indicating that CO ice is present and contributes to observed F466N absorption. The most strongly absorbed stars in F466N are extincted by ∼2 mag, corresponding to >80% flux loss. This high observed absorption requires very high column densities of CO, and thus a total CO column that is in tension with standard CO abundance and/or gas-to-dust ratios. This result suggests the CO/H₂ratio and dust-to-gas ratio are greater in the Galactic Center than in the Galactic disk. Ice and/or gas absorption is observed even in the cloud outskirts, implying that additional caution is needed when interpreting stellar photometry in filters that overlap with ice bands throughout galactic centers. 

ABSTRACT G0.253+0.016, commonly referred to as ‘the Brick’ and located within the Central Molecular Zone, is one of the densest (≈103–4 cm−3) molecular clouds in the Galaxy to lack signatures of widespread star formation. We set out to constrain the origins of an arc-shaped molecular line emission feature located within the cloud. We determine that the arc, centred on $$\lbrace l_{0},b_{0}\rbrace =\lbrace 0{_{.}^{\circ}} 248,\, 0{_{.}^{\circ}} 018\rbrace$$, has a radius of 1.3 pc and kinematics indicative of the presence of a shell expanding at $$5.2^{+2.7}_{-1.9}$$ $$\mathrm{\, km\, s}^{-1}$$. Extended radio continuum emission fills the arc cavity and recombination line emission peaks at a similar velocity to the arc, implying that the molecular gas and ionized gas are physically related. The inferred Lyman continuum photon rate is NLyC = 1046.0–1047.9 photons s−1, consistent with a star of spectral type B1-O8.5, corresponding to a mass of ≈12–20 M⊙. We explore two scenarios for the origin of the arc: (i) a partial shell swept up by the wind of an interloper high-mass star and (ii) a partial shell swept up by stellar feedback resulting from in situ star formation. We favour the latter scenario, finding reasonable (factor of a few) agreement between its morphology, dynamics, and energetics and those predicted for an expanding bubble driven by the wind from a high-mass star. The immediate implication is that G0.253+0.016 may not be as quiescent as is commonly accepted. We speculate that the cloud may have produced a ≲103 M⊙ star cluster ≳0.4 Myr ago, and demonstrate that the high-extinction and stellar crowding observed towards G0.253+0.016 may help to obscure such a star cluster from detection.